Hi Marco,
Yes, I have used the 1.4XE on the 250SA. Based on images I made of the moon, it maintains excellent sharpness. However, if memory serves me correctly, the tele converter introduces some chromatic aberration most pronounced at the edges of the image, which negates the “superachromaticity” of the lens. Whether this is an issue for you depends on the subject matter and is purely subjective, but it’s certainly a functional setup and easy enough to test without too much expense (I haven’t looked for a while but I don’t think the 1.4XE is commanding premium prices). Or just crop. My solution was to get the 350 Tele-Superachromat + APO1.4XE! The APO1.4XE works flawlessly on the 350 but is NOT compatible with the 250SA owing to the protrusion that would physically clash with the main lens’s rear element (I tried). Hope this helps.
John