Hi Shashin,
I've just been rushing to catch a train but I'm now sitting with a bit of spare time so I thought I'd discuss a few things relating to metamerism.
The idea of metamerism doesn't have any reliance on a human observer, although the majority of literature talks about biological systems and you could be mistaken to think this was so.
The spectral energy of a system can be defined as the combination of the illuminant spectral power distribution, the surface reflectance function and the sensor spectral response (which for a bayer sensor is itself is a combination of the colour filter array tramission spectral response and the silicon spectral absorption).
So E is illuminant, S is the subject reflectance spectrum and C is the sensor response.
The "colour" of the object is then derived from three of these spectral energies using a tristimulus approximation.
Pr = E.S.Cr
Pg = E.S.Cg
Pb = E.S.Cb
However for a single colour in the tristimus you can have many different illuminants **or sensors** that will create the same colour
Pr = E.S1.C1r = E.S2.C2r
Pr = E1.S1.C1r = E2.S2.C1r
This is the scientific definition of metamerism
Now the situations I have shown you are drawn from the same mathematics.
The first example I showed with the ferns showed two substances that looked the same on one camera but different on another but on another camera they looked the same.
This would be because of the interaction of the substance spectral reflectance with the sensor absorption spectrum (this is a simplification as mentioned previously).
Now the main issue with this is that if my eye saw these two substances as different and I wanted to represent this in my photograph, I could not..
The second example showed a colour calibrated image using an IT8 target but where the cobalt blues and powder blues had shifted towards magenta to some extent on different sensors.
This isn't much different than the problems discussed in this paper about accurate painting reproduction.
http://www.rmimaging.com/information/color_accurate_photography.pdf
This exceptionally 'illuminating' paper explains the sorts of problems a photographer needs to be aware of when trying to reproduce images that match the typical human tristimulus response. It's well worth a read and I would recommend paying particular attention to the part about CCD spectral response and colour filters.
The paper also explains why very strong infra red filters are not installed in cameras by default..
Tim